New method for sodium-catalyzed synthesis of Carbon Nanotubes

News Excerpt:

Researchers at the Institute of Advanced Study in Science and Technology (IASST), an autonomous institute of the Department of Science and Technology (DST), have pioneered a novel method for directly synthesising CNTs on glass substrates at a temperature of 750 °C.

  • It could catalyse energy research, biomedical fields, and optoelectronics, rechargeable batteries & flexible electronics.

CNT:

  • Carbon nanotubes (CNTs) are pivotal in advancing modern technology by showcasing extraordinary properties. 
  • They have found applications in diverse fields, including rechargeable batteries, flexible electronics, aerospace, transparent electrodes, touch screens, supercapacitors, and medicine. 
  • However, conventional CNT synthesis methods require high temperatures (~1000 0C) and metal catalysts (Fe, Co, and Ni). 
  • These catalysts pose biocompatibility concerns for potential biomedical applications. 
  • Among all the elements within the glass, sodium (Na) emerges as the primary catalyst for initiating CNT growth, and analysis evidences the same. 
  • It has also been observed that the Na present in the as-grown CNTs can be easily removed by washing the Na-containing CNTs with deionized water.

About the experiment: 

  • The experiment is performed using the Plasma Enhanced Chemical Vapour Deposition Technique (PECVD), where plasma is generated using a specially designed spiral-shaped fused hollow cathode source. 
  • This innovative process circumvents the need for elevated temperatures and eliminates the necessity for a transition metal catalyst. 
  • Furthermore, this synthesis is executed under atmospheric pressure, adding commendable cost-effectiveness to its advantages compared to counterparts in the field.
  • Benefits from the experiment: 
    • Decrease in temperature from conventional CNT (1000 to 750).
    • Na as a catalyst is easily removed compared to Fe, Co, and Ni (The challenge of removing these catalysts from CNTs adds a significant cost highlighting the urgent need for cleaner, more sustainable CNT synthesis methods).

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